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This article in SSSAJ

  1. Vol. 50 No. 6, p. 1618-1622
     
    Received: Feb 24, 1986
    Published: Nov, 1986


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doi:10.2136/sssaj1986.03615995005000060047x

Clinoptilolite in South Texas Soils1

  1. Douglas W. Ming and
  2. Joe B. Dixon2

Abstract

Abstract

Clinoptilolite, Cax(Na,K)6-2x{Al6Si30O72}·24H2O, frequently has been recognized in Cenozoic volcanogenic sedimentary rocks; however, its occurrence in soils has received little attention. In the course of this study, clinoptilolite was identified in calcareous soils derived from volcanic-rich sediments of the Catahoula Formation in south Texas. The mineralogical properties of clinoptilolite were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), electron microprobe analysis, and analysis of exchangeable cations. About 2 to 5% clinoptilolite by weight was found in the A and B horizons and concentrations progressively increased with depth to as high as 20% in the C horizons. No differences in the zeolite structural framework or Si/Al atomic ratio were detected throughout the soil profiles examined. Unlike Na- and K-saturated clinoptilolites in sedimentary deposits, clinoptilolite in these calcareous soils was predominantly Ca-saturated. Clinoptilolite was concentrated in the silt fractions as clusters of closely spaced laths that were 1 to 2 µm in thickness and 5 to 10 µm in length. Aggregates of the crystal plates and laths were as large as 50 to 60 µm in diam. Clinoptilolite in these soils appeared to have been inherited from zeolite-rich, tuffaceous parent materials. The smooth, angular, euhedral nature of the clinoptilolite crystals indicated their relative stability. Exceptional, slightly pitted and fractured crystals were observed in the A and B horizons indicating minimal weathering.

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